If you'd like to deploy VMware Player in your Enterprise you need to extract the MSI setup from the standard setup. You need to download the normal VMware-player-4.0.1-528992.exe file from VMware site. Than just launch these installer .exe, wait until the setup shows the "Welcome to the installation wizard for VMware Player", but don't install the Player. While the setup is launched setup creates a folder in C:\Users\%username%\AppData\Local\Temp\vmware_[random number]. Make a copy of this folder to your distribution share. Cancel the launched setup. Now you have the required MSI file vmware player.msi in the copied folder.
If you try to deploy VMware Player 4.0.0-471780 or 4.0.1-528992 to your Desktops via Active Directory you will expierence some major difficulties. At very first it's not possible to install at all. After some investigation it looks like very many others reported this bug in the VMware Community Forums, but nobody came up with a solution.
